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One-pot reductive amination of carbonyl compounds with nitro compounds over a Ni/NiO composite

Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H(2) as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common het...

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Detalles Bibliográficos
Autores principales: Kita, Yusuke, Kai, Sayaka, Supriadi Rustad, Lesandre Binti, Kamata, Keigo, Hara, Michikazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056697/
https://www.ncbi.nlm.nih.gov/pubmed/35516507
http://dx.doi.org/10.1039/d0ra06937j
Descripción
Sumario:Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H(2) as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common heterogeneous Ni catalysts.