Cargando…
Donor–acceptor duality of the transition-metal-like B(2) core in core–shell-like metallo-borospherenes La(3)&[B(2)@B(17)](−) and La(3)&[B(2)@B(18)](−)
Transition-metal doping induces dramatic structural changes and leads to earlier planar → tubular → spherical → core–shell-like structural transitions in boron clusters. Inspired by the newly discovered spherical trihedral metallo-borospherene D(3h) La(3)&B(18)(−) (1) (Chen, et al., Nat. Commun....
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056772/ https://www.ncbi.nlm.nih.gov/pubmed/35519037 http://dx.doi.org/10.1039/d0ra06769e |