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On single-electron magnesium bonding formation and the effect of methyl substitution
The complexes formed between MgX(2) (X = F, H) molecules and alkyl radicals Y [Y = CH(3), CH(2)CH(3), CH(CH(3))(2), and C(CH(3))(3)] have been characterized by using quantum chemical methods. The binding distance in all cases is less than the sum of vdW radii of Mg and C, indicating the formation of...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056782/ https://www.ncbi.nlm.nih.gov/pubmed/35514394 http://dx.doi.org/10.1039/d0ra06591a |