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On single-electron magnesium bonding formation and the effect of methyl substitution

The complexes formed between MgX(2) (X = F, H) molecules and alkyl radicals Y [Y = CH(3), CH(2)CH(3), CH(CH(3))(2), and C(CH(3))(3)] have been characterized by using quantum chemical methods. The binding distance in all cases is less than the sum of vdW radii of Mg and C, indicating the formation of...

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Detalles Bibliográficos
Autores principales:	Yu, Dan, Wu, Di, Liu, Jing-Yao, Li, Si-Yi, Li, Ying
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056782/ https://www.ncbi.nlm.nih.gov/pubmed/35514394 http://dx.doi.org/10.1039/d0ra06591a

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