Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex

Four tetrahydroquinoline-based chiral carbene precursors were synthesized using unsymmetrical N,N′-diarylformamidines and chiral 2-allyloxiranes as starting materials. A representative NHC–gold complex has been prepared and fully characterized, the crystal structure of which reveals an intramolecula...

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Detalles Bibliográficos
Autores principales: Zhan, Licheng, Zhang, Gengtao, Wang, Jiwei, Zhang, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056819/
https://www.ncbi.nlm.nih.gov/pubmed/35515693
http://dx.doi.org/10.1039/d0ra07271k
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author Zhan, Licheng
Zhang, Gengtao
Wang, Jiwei
Zhang, Jun
author_facet Zhan, Licheng
Zhang, Gengtao
Wang, Jiwei
Zhang, Jun
author_sort Zhan, Licheng
collection PubMed
description Four tetrahydroquinoline-based chiral carbene precursors were synthesized using unsymmetrical N,N′-diarylformamidines and chiral 2-allyloxiranes as starting materials. A representative NHC–gold complex has been prepared and fully characterized, the crystal structure of which reveals an intramolecular Au⋯H–C(sp(3)) interaction between Au(i) and the hydrogen atom of the isopropyl moiety in the N-aryl group.
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spelling pubmed-90568192022-05-04 Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex Zhan, Licheng Zhang, Gengtao Wang, Jiwei Zhang, Jun RSC Adv Chemistry Four tetrahydroquinoline-based chiral carbene precursors were synthesized using unsymmetrical N,N′-diarylformamidines and chiral 2-allyloxiranes as starting materials. A representative NHC–gold complex has been prepared and fully characterized, the crystal structure of which reveals an intramolecular Au⋯H–C(sp(3)) interaction between Au(i) and the hydrogen atom of the isopropyl moiety in the N-aryl group. The Royal Society of Chemistry 2020-09-23 /pmc/articles/PMC9056819/ /pubmed/35515693 http://dx.doi.org/10.1039/d0ra07271k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhan, Licheng
Zhang, Gengtao
Wang, Jiwei
Zhang, Jun
Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title_full Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title_fullStr Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title_full_unstemmed Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title_short Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
title_sort syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral nhc–au(i) complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056819/
https://www.ncbi.nlm.nih.gov/pubmed/35515693
http://dx.doi.org/10.1039/d0ra07271k
work_keys_str_mv AT zhanlicheng synthesesoftetrahydroquinolinebasedchiralcarbeneprecursorsandtherelatedchiralnhcauicomplex
AT zhanggengtao synthesesoftetrahydroquinolinebasedchiralcarbeneprecursorsandtherelatedchiralnhcauicomplex
AT wangjiwei synthesesoftetrahydroquinolinebasedchiralcarbeneprecursorsandtherelatedchiralnhcauicomplex
AT zhangjun synthesesoftetrahydroquinolinebasedchiralcarbeneprecursorsandtherelatedchiralnhcauicomplex

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