Synthesis and characterization of MOFs constructed from 5-(benzimidazole-1-yl)isophthalic acid and highly selective fluorescence detection of Fe(iii) and Cr(vi) in water

In this work, four novel metal–organic frameworks [Cd(bipa)](n) (1), {[Zn(2)(bipa)(2)]·2C(2)H(5)OH}(n) (2), {[Co(bipa)]·C(2)H(5)OH}(n) (3), {[Ni(bipa)(2)]·2DMA}(n) (4), (H(2)bipa = 5-(benzimidazole-1-yl)isophthalic acid) were successfully synthesized under solvothermal conditions. Complexes 1–4 were characterized by powder X-ray diffraction, elemental analysis, infrared spectroscopy and thermogravimetric analysis. Interestingly, the coordination patterns and 3D network structures of complexes 1–3 are very similar, while complex 4 is relatively unique. Complexes 1–2 exhibit potential fluorescent properties. Complex 1 can selectively and sensitively detect trace Fe(iii) and Cr(vi) in water by fluorescence quenching detection, and the quenching mechanism is further discussed.