Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold

An efficient 2-furyl gold–carbene promoted synthetic method was developed for the formation of dihydroquinazolinones from enynones by dual insertion of anthranilamides. In this organic transformation a new C–O and two C–N bond formations occurred and dihydroquinazolinones were obtained with a quater...

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Autores principales: Kadiyala, Veerabhushanam, Kumar, Perla Bharath, Sunil, Komalla, Raju, Chittala Emmaniel, Sridhar, Balasubramanian, Karunakar, Galla V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056963/
https://www.ncbi.nlm.nih.gov/pubmed/35517079
http://dx.doi.org/10.1039/d0ra06537d
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author Kadiyala, Veerabhushanam
Kumar, Perla Bharath
Sunil, Komalla
Raju, Chittala Emmaniel
Sridhar, Balasubramanian
Karunakar, Galla V.
author_facet Kadiyala, Veerabhushanam
Kumar, Perla Bharath
Sunil, Komalla
Raju, Chittala Emmaniel
Sridhar, Balasubramanian
Karunakar, Galla V.
author_sort Kadiyala, Veerabhushanam
collection PubMed
description An efficient 2-furyl gold–carbene promoted synthetic method was developed for the formation of dihydroquinazolinones from enynones by dual insertion of anthranilamides. In this organic transformation a new C–O and two C–N bond formations occurred and dihydroquinazolinones were obtained with a quaternary centre in moderate to very good yields in one-pot synthesis.
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spelling pubmed-90569632022-05-04 Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold Kadiyala, Veerabhushanam Kumar, Perla Bharath Sunil, Komalla Raju, Chittala Emmaniel Sridhar, Balasubramanian Karunakar, Galla V. RSC Adv Chemistry An efficient 2-furyl gold–carbene promoted synthetic method was developed for the formation of dihydroquinazolinones from enynones by dual insertion of anthranilamides. In this organic transformation a new C–O and two C–N bond formations occurred and dihydroquinazolinones were obtained with a quaternary centre in moderate to very good yields in one-pot synthesis. The Royal Society of Chemistry 2020-09-28 /pmc/articles/PMC9056963/ /pubmed/35517079 http://dx.doi.org/10.1039/d0ra06537d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Kadiyala, Veerabhushanam
Kumar, Perla Bharath
Sunil, Komalla
Raju, Chittala Emmaniel
Sridhar, Balasubramanian
Karunakar, Galla V.
Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title_full Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title_fullStr Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title_full_unstemmed Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title_short Gold(iii) promoted formation of dihydroquinazolinones: double X–H activation by gold
title_sort gold(iii) promoted formation of dihydroquinazolinones: double x–h activation by gold
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056963/
https://www.ncbi.nlm.nih.gov/pubmed/35517079
http://dx.doi.org/10.1039/d0ra06537d
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