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Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity

In this study, we have reported selective synthesis of bismuth molybdate (γ-Bi(2)M(2)O(6)) nanoparticles (NPs) under different pH conditions for photocatalytic degradation of methylene blue (MB), reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and antimicrobial activities. The synthesis of...

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Autores principales: Lavakusa, B., Rama Devi, Dharmaoth, Belachew, Neway, Basavaiah, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057020/
https://www.ncbi.nlm.nih.gov/pubmed/35517965
http://dx.doi.org/10.1039/d0ra07459d
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author Lavakusa, B.
Rama Devi, Dharmaoth
Belachew, Neway
Basavaiah, K.
author_facet Lavakusa, B.
Rama Devi, Dharmaoth
Belachew, Neway
Basavaiah, K.
author_sort Lavakusa, B.
collection PubMed
description In this study, we have reported selective synthesis of bismuth molybdate (γ-Bi(2)M(2)O(6)) nanoparticles (NPs) under different pH conditions for photocatalytic degradation of methylene blue (MB), reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and antimicrobial activities. The synthesis of pure phase γ-Bi(2)M(2)O(6) at pH = 3 was confirmed by X-ray diffraction (XRD) and Raman analysis. A single hexagonal morphology was obtained at pH = 3 which shows the formation of the pure phase γ-Bi(2)M(2)O(6) NPs. The mixed morphologies (hexagonal and spherical) were observed at different pH values other than pH = 3. The bandgap energy of all the synthesized Bi(2)M(2)O(6) NPs is found in the visible region (2.48–2.59 eV). The photocatalytic activity of bismuth molybdate (BM) NPs was examined by the degradation of MB under visible light irradiation. Results show that 95.44% degradation efficiency was achieved by pure γ-Bi(2)M(2)O(6) NPs compared to mixed phases (γ-Bi(2)M(2)O(6), α-Bi(2)M(2)O(6) and β-Bi(2)M(2)O(6)) synthesized at pH = 1.5 and 5. Moreover, the degradation efficiency of γ-Bi(2)M(2)O(6) was enhanced to 98.89% by the addition of H(2)O(2). The effective catalytic activity of γ-Bi(2)M(2)O(6) was observed during the reduction of 4-NP to 4-AP by NaBH(4). Potential antibacterial and antifungal activity of γ-Bi(2)M(2)O(6) was observed, which gives a basis for further study in the development of antibiotics.
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spelling pubmed-90570202022-05-04 Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity Lavakusa, B. Rama Devi, Dharmaoth Belachew, Neway Basavaiah, K. RSC Adv Chemistry In this study, we have reported selective synthesis of bismuth molybdate (γ-Bi(2)M(2)O(6)) nanoparticles (NPs) under different pH conditions for photocatalytic degradation of methylene blue (MB), reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and antimicrobial activities. The synthesis of pure phase γ-Bi(2)M(2)O(6) at pH = 3 was confirmed by X-ray diffraction (XRD) and Raman analysis. A single hexagonal morphology was obtained at pH = 3 which shows the formation of the pure phase γ-Bi(2)M(2)O(6) NPs. The mixed morphologies (hexagonal and spherical) were observed at different pH values other than pH = 3. The bandgap energy of all the synthesized Bi(2)M(2)O(6) NPs is found in the visible region (2.48–2.59 eV). The photocatalytic activity of bismuth molybdate (BM) NPs was examined by the degradation of MB under visible light irradiation. Results show that 95.44% degradation efficiency was achieved by pure γ-Bi(2)M(2)O(6) NPs compared to mixed phases (γ-Bi(2)M(2)O(6), α-Bi(2)M(2)O(6) and β-Bi(2)M(2)O(6)) synthesized at pH = 1.5 and 5. Moreover, the degradation efficiency of γ-Bi(2)M(2)O(6) was enhanced to 98.89% by the addition of H(2)O(2). The effective catalytic activity of γ-Bi(2)M(2)O(6) was observed during the reduction of 4-NP to 4-AP by NaBH(4). Potential antibacterial and antifungal activity of γ-Bi(2)M(2)O(6) was observed, which gives a basis for further study in the development of antibiotics. The Royal Society of Chemistry 2020-10-06 /pmc/articles/PMC9057020/ /pubmed/35517965 http://dx.doi.org/10.1039/d0ra07459d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Lavakusa, B.
Rama Devi, Dharmaoth
Belachew, Neway
Basavaiah, K.
Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title_full Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title_fullStr Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title_full_unstemmed Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title_short Selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
title_sort selective synthesis of visible light active γ-bismuth molybdate nanoparticles for efficient photocatalytic degradation of methylene blue, reduction of 4-nitrophenol, and antimicrobial activity
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057020/
https://www.ncbi.nlm.nih.gov/pubmed/35517965
http://dx.doi.org/10.1039/d0ra07459d
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