Nanocellulose enriches enantiomers in asymmetric aldol reactions

Cellulose nanofibers obtained from wood pulp by TEMPO-mediated oxidation acted as a chiral enhancer in direct aldol reactions of 4-nitrobenzaldehyde and cyclopentanone with (S)-proline as an organocatalyst. Surprisingly, catalytically inactive TEMPO-oxidized cellulose nanofibers enriched the (R,R)-e...

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Detalles Bibliográficos
Autores principales: Ranaivoarimanana, Naliharifetra Jessica, Habaki, Xin, Uto, Takuya, Kanomata, Kyohei, Yui, Toshifumi, Kitaoka, Takuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057038/
https://www.ncbi.nlm.nih.gov/pubmed/35521245
http://dx.doi.org/10.1039/d0ra07412h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057038/
https://www.ncbi.nlm.nih.gov/pubmed/35521245
http://dx.doi.org/10.1039/d0ra07412h

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