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Nanocellulose enriches enantiomers in asymmetric aldol reactions
Cellulose nanofibers obtained from wood pulp by TEMPO-mediated oxidation acted as a chiral enhancer in direct aldol reactions of 4-nitrobenzaldehyde and cyclopentanone with (S)-proline as an organocatalyst. Surprisingly, catalytically inactive TEMPO-oxidized cellulose nanofibers enriched the (R,R)-e...
Autores principales: | Ranaivoarimanana, Naliharifetra Jessica, Habaki, Xin, Uto, Takuya, Kanomata, Kyohei, Yui, Toshifumi, Kitaoka, Takuya |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057038/ https://www.ncbi.nlm.nih.gov/pubmed/35521245 http://dx.doi.org/10.1039/d0ra07412h |
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