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Attempted characterisation of phenanthrene-4,5-quinone and electrochemical synthesis of violanthrone-16,17-quinone. How does the stability of bay quinones correlate with structural and electronic parameters?

In bay quinones, two carbonyl moieties are forced into close proximity by their spatial arrangement, resulting in an interesting axially chiral and nonplanar structure. Two representatives of this little-explored class of compounds were investigated experimentally in this work. Electrochemical oxida...

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Detalles Bibliográficos
Autores principales: Wilkinson, Dylan, Cioncoloni, Giacomo, Symes, Mark D., Bucher, Götz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057194/
https://www.ncbi.nlm.nih.gov/pubmed/35515143
http://dx.doi.org/10.1039/d0ra06519f

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