Asymmetric 1,3-dipolar cycloaddition reaction of chiral 1-alkyl-1,2-diphospholes with diphenyldiazomethane

The 1,3-dipolar cycloaddition of chiral 1-alkyl-1,2-diphosphacyclopenta-2,4-dienes ((1-(−)-menthyl)oxymethyl-1,2-diphosphole and 1-(+)-neomenthyl-1,2-diphosphole) with diphenyldiazomethane leads to novel P-chiral bicyclic phosphiranes having six chiral centers. The degree of diastereoselectivity dep...

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Detalles Bibliográficos
Autores principales: Ganushevich, Yulia, Zagidullin, Almaz, Kondrashova, Svetlana, Latypov, Shamil, Miluykov, Vasili, Lönnecke, Peter, Hey-Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057342/
https://www.ncbi.nlm.nih.gov/pubmed/35518401
http://dx.doi.org/10.1039/d0ra08080b

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