Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage

A Au(i)–N-heterocyclic-carbene (NHC)-edged Pd(6)L(12) molecular metal–organic cage is assembled from a Au(i)–NHC-based bipyridyl bent ligand and Pd(2+). The octahedral cage structure is unambiguously established by NMR, electrospray ionization-mass spectrometry and single crystal X-ray crystallograp...

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Autores principales: Zeng, Lihua, Sun, Shujian, Wei, Zhang-Wen, Xin, Yu, Liu, Liping, Zhang, Jianyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057365/
https://www.ncbi.nlm.nih.gov/pubmed/35518404
http://dx.doi.org/10.1039/d0ra07509d
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author Zeng, Lihua
Sun, Shujian
Wei, Zhang-Wen
Xin, Yu
Liu, Liping
Zhang, Jianyong
author_facet Zeng, Lihua
Sun, Shujian
Wei, Zhang-Wen
Xin, Yu
Liu, Liping
Zhang, Jianyong
author_sort Zeng, Lihua
collection PubMed
description A Au(i)–N-heterocyclic-carbene (NHC)-edged Pd(6)L(12) molecular metal–organic cage is assembled from a Au(i)–NHC-based bipyridyl bent ligand and Pd(2+). The octahedral cage structure is unambiguously established by NMR, electrospray ionization-mass spectrometry and single crystal X-ray crystallography. The electrochemical behaviour was analyzed by cyclic voltammetry. The octahedral cage has a central cavity for guest binding, and is capable of encapsulating PF(6)(−) and BF(4)(−) anions within the cavity.
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spelling pubmed-90573652022-05-04 Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage Zeng, Lihua Sun, Shujian Wei, Zhang-Wen Xin, Yu Liu, Liping Zhang, Jianyong RSC Adv Chemistry A Au(i)–N-heterocyclic-carbene (NHC)-edged Pd(6)L(12) molecular metal–organic cage is assembled from a Au(i)–NHC-based bipyridyl bent ligand and Pd(2+). The octahedral cage structure is unambiguously established by NMR, electrospray ionization-mass spectrometry and single crystal X-ray crystallography. The electrochemical behaviour was analyzed by cyclic voltammetry. The octahedral cage has a central cavity for guest binding, and is capable of encapsulating PF(6)(−) and BF(4)(−) anions within the cavity. The Royal Society of Chemistry 2020-10-27 /pmc/articles/PMC9057365/ /pubmed/35518404 http://dx.doi.org/10.1039/d0ra07509d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Zeng, Lihua
Sun, Shujian
Wei, Zhang-Wen
Xin, Yu
Liu, Liping
Zhang, Jianyong
Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title_full Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title_fullStr Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title_full_unstemmed Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title_short Confinement of a Au–N-heterocyclic carbene in a Pd(6)L(12) metal–organic cage
title_sort confinement of a au–n-heterocyclic carbene in a pd(6)l(12) metal–organic cage
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057365/
https://www.ncbi.nlm.nih.gov/pubmed/35518404
http://dx.doi.org/10.1039/d0ra07509d
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