Silver ion-doped CdTe quantum dots as fluorescent probe for Hg(2+) detection

Mercury(ii), which is a well-known toxic species, exists in the industrial waste water in many cases. In the present work, CdTe quantum dots (QDs) are studied as a fluorescence probe for Hg(2+) detection. Ag ions are induced to QDs to enlarge their detection concentration range. l-cysteine is employed in the QD-based fluorescence probe to connect QDs with Hg(2+). X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy results indicate the formation of zinc blende CdTe QDs with sizes of ∼5 nm and the existence of Ag(+) in crystalline CdTe. Photoluminescence (PL) spectra and PL decay spectra were acquired to investigate the emission mechanism of Ag-doped CdTe QDs, revealing multi-emission in QD samples with higher concentrations of Ag(+) doping. The highest PL quantum yield of the QD samples was 59.4%. Furthermore, the relationship between the fluorescence intensity and the concentration of Hg(2+) has been established. Two linear relationships were obtained for the plot of F/F(0) against Hg(2+) concentration, enlarging the detection concentration range of Hg(2+).