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An orifice design: water insertion into C(60)

Using an open-cage C(60) derivative possessing an orifice designed on the basis of computational studies, we have experimentally demonstrated the quantitative encapsulation of H(2)O as well as effective conversion into H(2)O@C(60) in an overall yield remarkably higher than the previously reported me...

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Detalles Bibliográficos
Autores principales: Hashikawa, Yoshifumi, Kizaki, Kazuro, Hirose, Takashi, Murata, Yasujiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057476/
https://www.ncbi.nlm.nih.gov/pubmed/35520847
http://dx.doi.org/10.1039/d0ra09067k
Descripción
Sumario:Using an open-cage C(60) derivative possessing an orifice designed on the basis of computational studies, we have experimentally demonstrated the quantitative encapsulation of H(2)O as well as effective conversion into H(2)O@C(60) in an overall yield remarkably higher than the previously reported methods by ca. 2–5 times.