Use of pyrazoles as ligands greatly enhances the catalytic activity of titanium iso-propoxide for the ring-opening polymerization of l-lactide: a cooperation effect

Using TiO(i)Pr(4) with a pyrazole ligand for one-pot LA polymerization improved catalytic activity compared with using TiO(i)Pr(4) only. At 60 °C, TiO(i)Pr(4) with (fur)Pz exhibited a higher catalytic activity (approximately 3-fold) than TiO(i)Pr(4). At room temperature, TiO(i)Pr(4) with (Bu)Pz exhi...

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Detalles Bibliográficos
Autores principales: Wang, Tzu-Fang, Kosuru, Someswara Rao, Yu, Shu-Chun, Chang, Yung-Chi, Lai, Hsin-Yu, Chang, Yu-Lun, Wu, Kuo-Hui, Ding, Shangwu, Chen, Hsuan-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057761/
https://www.ncbi.nlm.nih.gov/pubmed/35519227
http://dx.doi.org/10.1039/d0ra07824g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057761/
https://www.ncbi.nlm.nih.gov/pubmed/35519227
http://dx.doi.org/10.1039/d0ra07824g

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