Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions

Monometallic (Pd, Ru or Rh) and bimetallic (Pd(0.5)–Ru(0.5)) alloy NPs catalysts were examined for the hydrogenation of quinoline. Pd–Ru alloy catalyst showed superior catalytic activity to the traditional Rh catalyst. The characterization of Pd(0.5)–Ru(0.5) catalysts, HAADF-EDX mapping and XPS anal...

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Autores principales: Chaudhari, Chandan, Sato, Katsutoshi, Nishida, Yoshihide, Yamamoto, Tomokazu, Toriyama, Takaaki, Matsumura, Syo, Ikeda, Yasuyuki, Terada, Kenji, Abe, Naoya, Kusuda, Kohei, Kitagawa, Hiroshi, Nagaoka, Katsutoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058507/
https://www.ncbi.nlm.nih.gov/pubmed/35517135
http://dx.doi.org/10.1039/d0ra09981c
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author Chaudhari, Chandan
Sato, Katsutoshi
Nishida, Yoshihide
Yamamoto, Tomokazu
Toriyama, Takaaki
Matsumura, Syo
Ikeda, Yasuyuki
Terada, Kenji
Abe, Naoya
Kusuda, Kohei
Kitagawa, Hiroshi
Nagaoka, Katsutoshi
author_facet Chaudhari, Chandan
Sato, Katsutoshi
Nishida, Yoshihide
Yamamoto, Tomokazu
Toriyama, Takaaki
Matsumura, Syo
Ikeda, Yasuyuki
Terada, Kenji
Abe, Naoya
Kusuda, Kohei
Kitagawa, Hiroshi
Nagaoka, Katsutoshi
author_sort Chaudhari, Chandan
collection PubMed
description Monometallic (Pd, Ru or Rh) and bimetallic (Pd(0.5)–Ru(0.5)) alloy NPs catalysts were examined for the hydrogenation of quinoline. Pd–Ru alloy catalyst showed superior catalytic activity to the traditional Rh catalyst. The characterization of Pd(0.5)–Ru(0.5) catalysts, HAADF-EDX mapping and XPS analysis suggested that the alloy state of PdRu catalysts remained unchanged in the recovered catalyst. Furthermore, the catalyst was highly selective for the hydrogenation of different arenes.
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spelling pubmed-90585072022-05-04 Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions Chaudhari, Chandan Sato, Katsutoshi Nishida, Yoshihide Yamamoto, Tomokazu Toriyama, Takaaki Matsumura, Syo Ikeda, Yasuyuki Terada, Kenji Abe, Naoya Kusuda, Kohei Kitagawa, Hiroshi Nagaoka, Katsutoshi RSC Adv Chemistry Monometallic (Pd, Ru or Rh) and bimetallic (Pd(0.5)–Ru(0.5)) alloy NPs catalysts were examined for the hydrogenation of quinoline. Pd–Ru alloy catalyst showed superior catalytic activity to the traditional Rh catalyst. The characterization of Pd(0.5)–Ru(0.5) catalysts, HAADF-EDX mapping and XPS analysis suggested that the alloy state of PdRu catalysts remained unchanged in the recovered catalyst. Furthermore, the catalyst was highly selective for the hydrogenation of different arenes. The Royal Society of Chemistry 2020-12-15 /pmc/articles/PMC9058507/ /pubmed/35517135 http://dx.doi.org/10.1039/d0ra09981c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Chaudhari, Chandan
Sato, Katsutoshi
Nishida, Yoshihide
Yamamoto, Tomokazu
Toriyama, Takaaki
Matsumura, Syo
Ikeda, Yasuyuki
Terada, Kenji
Abe, Naoya
Kusuda, Kohei
Kitagawa, Hiroshi
Nagaoka, Katsutoshi
Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title_full Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title_fullStr Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title_full_unstemmed Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title_short Chemoselective hydrogenation of heteroarenes and arenes by Pd–Ru–PVP under mild conditions
title_sort chemoselective hydrogenation of heteroarenes and arenes by pd–ru–pvp under mild conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058507/
https://www.ncbi.nlm.nih.gov/pubmed/35517135
http://dx.doi.org/10.1039/d0ra09981c
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