Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes

The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.

Detalles Bibliográficos
Autores principales: Matheny, Jonathon P., Yamanushkin, Pavel M., Petillo, Peter A., Rubin, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058510/
https://www.ncbi.nlm.nih.gov/pubmed/35517142
http://dx.doi.org/10.1039/d0ra09014j
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author Matheny, Jonathon P.
Yamanushkin, Pavel M.
Petillo, Peter A.
Rubin, Michael
author_facet Matheny, Jonathon P.
Yamanushkin, Pavel M.
Petillo, Peter A.
Rubin, Michael
author_sort Matheny, Jonathon P.
collection PubMed
description The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.
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spelling pubmed-90585102022-05-04 Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes Matheny, Jonathon P. Yamanushkin, Pavel M. Petillo, Peter A. Rubin, Michael RSC Adv Chemistry The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones. The Royal Society of Chemistry 2020-12-15 /pmc/articles/PMC9058510/ /pubmed/35517142 http://dx.doi.org/10.1039/d0ra09014j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Matheny, Jonathon P.
Yamanushkin, Pavel M.
Petillo, Peter A.
Rubin, Michael
Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title_full Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title_fullStr Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title_full_unstemmed Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title_short Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
title_sort facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9058510/
https://www.ncbi.nlm.nih.gov/pubmed/35517142
http://dx.doi.org/10.1039/d0ra09014j
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AT petillopetera facileassemblyof15diazocan2onesviacyclizationoftetheredsulfonamidestocyclopropenes
AT rubinmichael facileassemblyof15diazocan2onesviacyclizationoftetheredsulfonamidestocyclopropenes

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