A divergent approach for the synthesis of (hydroxymethyl)furfural (HMF) from spent aromatic biomass-derived (chloromethyl)furfural (CMF) as a renewable feedstock

Extraction of commercial essential oil from several aromatic species belonging to the genus Cymbopogon results in the accumulation of huge spent aromatic waste which does not have high value application; instead, the majority is burned or disposed of to vacate fields. Open burning of spent aromatic biomass causes deterioration of the surrounding air quality. Therefore, a new protocol has been developed for chemical processing of spent biomass to obtain 5-(chloromethyl)furfural (CMF) with high selectivity (∼80%) and yields (∼26 wt% or ∼76 mol% with respect to pre-treated biomass) via refluxing in aqueous HCl in the presence of NaCl as a cheap catalyst. No black tar formation and gasification were observed in the processing of the spent aromatic biomass. Spent aromatic waste-derived CMF was further converted to 5-(hydroxymethyl)furfural (HMF) in good yields by a novel one pot method using iodosylbenzene (PhIO) as a reagent under mild reaction conditions.