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A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation

A novel 3D Cd(ii) coordination polymer {[Cd(ddpa)(2,2′-bpy)]·H(2)O}(n) (1) (H(2)ddpa = 5,10-dioxo-5,10-dihydro-4,9-dioxapyrene-2,7-dicarboxylic acid, 2,2′-bpy = 2,2′-bipyridine) is hydrothermally synthesized in situ, and the influencing factors and mechanism for the in situ reaction are briefly disc...

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Autores principales: Wang, Ji-Jiang, Cao, Zhuang, Wang, Xiao, Tang, Long, Hou, Xiang-Yang, Ju, Ping, Ren, Yi-Xia, Chen, Xiao-Li, Zhang, Yu-Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059329/
https://www.ncbi.nlm.nih.gov/pubmed/35521577
http://dx.doi.org/10.1039/c8ra06112b
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author Wang, Ji-Jiang
Cao, Zhuang
Wang, Xiao
Tang, Long
Hou, Xiang-Yang
Ju, Ping
Ren, Yi-Xia
Chen, Xiao-Li
Zhang, Yu-Qi
author_facet Wang, Ji-Jiang
Cao, Zhuang
Wang, Xiao
Tang, Long
Hou, Xiang-Yang
Ju, Ping
Ren, Yi-Xia
Chen, Xiao-Li
Zhang, Yu-Qi
author_sort Wang, Ji-Jiang
collection PubMed
description A novel 3D Cd(ii) coordination polymer {[Cd(ddpa)(2,2′-bpy)]·H(2)O}(n) (1) (H(2)ddpa = 5,10-dioxo-5,10-dihydro-4,9-dioxapyrene-2,7-dicarboxylic acid, 2,2′-bpy = 2,2′-bipyridine) is hydrothermally synthesized in situ, and the influencing factors and mechanism for the in situ reaction are briefly discussed. The synthesis of 1 requires the formation of a new C–O ester bond. This current study confirms that metal ions and N-donor ligands play important roles in the domination of the in situ ligand from 6,6′-dinitro-2,2′,4,4′-biphenyltetracarboxylic acid (H(4)dbta). Furthermore, the structure, thermal stability and photoluminescent property of 1 are also investigated.
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spelling pubmed-90593292022-05-04 A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation Wang, Ji-Jiang Cao, Zhuang Wang, Xiao Tang, Long Hou, Xiang-Yang Ju, Ping Ren, Yi-Xia Chen, Xiao-Li Zhang, Yu-Qi RSC Adv Chemistry A novel 3D Cd(ii) coordination polymer {[Cd(ddpa)(2,2′-bpy)]·H(2)O}(n) (1) (H(2)ddpa = 5,10-dioxo-5,10-dihydro-4,9-dioxapyrene-2,7-dicarboxylic acid, 2,2′-bpy = 2,2′-bipyridine) is hydrothermally synthesized in situ, and the influencing factors and mechanism for the in situ reaction are briefly discussed. The synthesis of 1 requires the formation of a new C–O ester bond. This current study confirms that metal ions and N-donor ligands play important roles in the domination of the in situ ligand from 6,6′-dinitro-2,2′,4,4′-biphenyltetracarboxylic acid (H(4)dbta). Furthermore, the structure, thermal stability and photoluminescent property of 1 are also investigated. The Royal Society of Chemistry 2019-01-02 /pmc/articles/PMC9059329/ /pubmed/35521577 http://dx.doi.org/10.1039/c8ra06112b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Ji-Jiang
Cao, Zhuang
Wang, Xiao
Tang, Long
Hou, Xiang-Yang
Ju, Ping
Ren, Yi-Xia
Chen, Xiao-Li
Zhang, Yu-Qi
A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title_full A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title_fullStr A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title_full_unstemmed A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title_short A novel 3D Cd(ii) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation
title_sort novel 3d cd(ii) coordination polymer generated via in situ ligand synthesis involving c–o ester bond formation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9059329/
https://www.ncbi.nlm.nih.gov/pubmed/35521577
http://dx.doi.org/10.1039/c8ra06112b
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