Cargando…
Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics
The conversion of carbon dioxide (CO(2)) into value-added organic compounds has received more and more attention over recent years, not only because this gas is one of the major anthropogenic greenhouse gases, but also because it has been regarded as an abundant, inexpensive, nontoxic, nonflammable,...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060502/ https://www.ncbi.nlm.nih.gov/pubmed/35518075 http://dx.doi.org/10.1039/c8ra10233c |
_version_ | 1784698517812412416 |
---|---|
author | Monfared, Aazam Mohammadi, Robab Hosseinian, Akram Sarhandi, Shahriar Kheirollahi Nezhad, Parvaneh Delir |
author_facet | Monfared, Aazam Mohammadi, Robab Hosseinian, Akram Sarhandi, Shahriar Kheirollahi Nezhad, Parvaneh Delir |
author_sort | Monfared, Aazam |
collection | PubMed |
description | The conversion of carbon dioxide (CO(2)) into value-added organic compounds has received more and more attention over recent years, not only because this gas is one of the major anthropogenic greenhouse gases, but also because it has been regarded as an abundant, inexpensive, nontoxic, nonflammable, and renewable one-carbon (C1) resource. Along these lines, the synthesis of five-membered cyclic carbonates employing CO(2) as a safe alternative to toxic reagents such as phosgene or its derivatives is of great interest because of their wide range of applications in organic synthesis. However, most of CO(2) incorporation reactions into carbonates are carried out in toxic and non-recyclable organic solvents. Furthermore, these transformations usually proceed at elevated pressures or supercritical CO(2) conditions. Recently, several catalytic systems have been developed that allow the synthesis of functionalized carbonates from the reaction of atmospheric CO(2) with corresponding epoxides under solvent-free conditions. This review is an attempt to summarize the most important advances and discoveries in this interesting research arena. The review is divided into three major sections. The first section will discuss ionic liquid catalyzed coupling reactions. The second will cover organocatalyzed reactions. The third focuses exclusively on metal-catalyzed fixations. Notably, the third section has been classified based on the metal element that carries out the catalysis (i.e. copper, palladium, zinc). |
format | Online Article Text |
id | pubmed-9060502 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90605022022-05-04 Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics Monfared, Aazam Mohammadi, Robab Hosseinian, Akram Sarhandi, Shahriar Kheirollahi Nezhad, Parvaneh Delir RSC Adv Chemistry The conversion of carbon dioxide (CO(2)) into value-added organic compounds has received more and more attention over recent years, not only because this gas is one of the major anthropogenic greenhouse gases, but also because it has been regarded as an abundant, inexpensive, nontoxic, nonflammable, and renewable one-carbon (C1) resource. Along these lines, the synthesis of five-membered cyclic carbonates employing CO(2) as a safe alternative to toxic reagents such as phosgene or its derivatives is of great interest because of their wide range of applications in organic synthesis. However, most of CO(2) incorporation reactions into carbonates are carried out in toxic and non-recyclable organic solvents. Furthermore, these transformations usually proceed at elevated pressures or supercritical CO(2) conditions. Recently, several catalytic systems have been developed that allow the synthesis of functionalized carbonates from the reaction of atmospheric CO(2) with corresponding epoxides under solvent-free conditions. This review is an attempt to summarize the most important advances and discoveries in this interesting research arena. The review is divided into three major sections. The first section will discuss ionic liquid catalyzed coupling reactions. The second will cover organocatalyzed reactions. The third focuses exclusively on metal-catalyzed fixations. Notably, the third section has been classified based on the metal element that carries out the catalysis (i.e. copper, palladium, zinc). The Royal Society of Chemistry 2019-01-29 /pmc/articles/PMC9060502/ /pubmed/35518075 http://dx.doi.org/10.1039/c8ra10233c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Monfared, Aazam Mohammadi, Robab Hosseinian, Akram Sarhandi, Shahriar Kheirollahi Nezhad, Parvaneh Delir Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title | Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title_full | Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title_fullStr | Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title_full_unstemmed | Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title_short | Cycloaddition of atmospheric CO(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
title_sort | cycloaddition of atmospheric co(2) to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060502/ https://www.ncbi.nlm.nih.gov/pubmed/35518075 http://dx.doi.org/10.1039/c8ra10233c |
work_keys_str_mv | AT monfaredaazam cycloadditionofatmosphericco2toepoxidesundersolventfreeconditionsastraightforwardroutetocarbonatesbygreenchemistrymetrics AT mohammadirobab cycloadditionofatmosphericco2toepoxidesundersolventfreeconditionsastraightforwardroutetocarbonatesbygreenchemistrymetrics AT hosseinianakram cycloadditionofatmosphericco2toepoxidesundersolventfreeconditionsastraightforwardroutetocarbonatesbygreenchemistrymetrics AT sarhandishahriar cycloadditionofatmosphericco2toepoxidesundersolventfreeconditionsastraightforwardroutetocarbonatesbygreenchemistrymetrics AT kheirollahinezhadparvanehdelir cycloadditionofatmosphericco2toepoxidesundersolventfreeconditionsastraightforwardroutetocarbonatesbygreenchemistrymetrics |