A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency

Atomically precise Au(13) nanoclusters stabilized by stibines catalyze the aldehyde–alkyne–amine coupling reaction more efficiently than those stabilized by thiols or phosphines. The nature of the catalytic activity is also different, and may be attributed to the weaker coordinating ability of the s...

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Detalles Bibliográficos
Autores principales: Li, Ying-Zhou, Leong, Weng Kee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060790/
https://www.ncbi.nlm.nih.gov/pubmed/35515902
http://dx.doi.org/10.1039/c9ra00933g
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author Li, Ying-Zhou
Leong, Weng Kee
author_facet Li, Ying-Zhou
Leong, Weng Kee
author_sort Li, Ying-Zhou
collection PubMed
description Atomically precise Au(13) nanoclusters stabilized by stibines catalyze the aldehyde–alkyne–amine coupling reaction more efficiently than those stabilized by thiols or phosphines. The nature of the catalytic activity is also different, and may be attributed to the weaker coordinating ability of the stibine ligands.
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spelling pubmed-90607902022-05-04 A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency Li, Ying-Zhou Leong, Weng Kee RSC Adv Chemistry Atomically precise Au(13) nanoclusters stabilized by stibines catalyze the aldehyde–alkyne–amine coupling reaction more efficiently than those stabilized by thiols or phosphines. The nature of the catalytic activity is also different, and may be attributed to the weaker coordinating ability of the stibine ligands. The Royal Society of Chemistry 2019-02-13 /pmc/articles/PMC9060790/ /pubmed/35515902 http://dx.doi.org/10.1039/c9ra00933g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Ying-Zhou
Leong, Weng Kee
A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title_full A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title_fullStr A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title_full_unstemmed A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title_short A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde–alkyne–amine (A(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
title_sort comparative study on atomically precise au nanoclusters as catalysts for the aldehyde–alkyne–amine (a(3)) coupling reaction: ligand effects on the nature of the catalysis and efficiency
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060790/
https://www.ncbi.nlm.nih.gov/pubmed/35515902
http://dx.doi.org/10.1039/c9ra00933g
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