Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst

N-heterocyclic carbene–palladium(ii)-catalyzed cross-coupling of benzylammonium salts with arylboronic acids for the synthesis of diarylmethane derivatives via C–N bond activation has been developed. Notably, in the presence of the easily prepared and bench-stable Pd-PEPPSI precatalyst, the Csp(3)–N...

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Detalles Bibliográficos
Autores principales: Wang, Tao, Guo, Jiarui, Wang, Xiaojuan, Guo, Han, Jia, Dingli, Wang, Hengjin, Liu, Lantao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060798/
https://www.ncbi.nlm.nih.gov/pubmed/35515917
http://dx.doi.org/10.1039/c8ra10439e
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author Wang, Tao
Guo, Jiarui
Wang, Xiaojuan
Guo, Han
Jia, Dingli
Wang, Hengjin
Liu, Lantao
author_facet Wang, Tao
Guo, Jiarui
Wang, Xiaojuan
Guo, Han
Jia, Dingli
Wang, Hengjin
Liu, Lantao
author_sort Wang, Tao
collection PubMed
description N-heterocyclic carbene–palladium(ii)-catalyzed cross-coupling of benzylammonium salts with arylboronic acids for the synthesis of diarylmethane derivatives via C–N bond activation has been developed. Notably, in the presence of the easily prepared and bench-stable Pd-PEPPSI precatalyst, the Csp(3)–N bond activation of the benzylammonium salt even proceeded smoothly in isopropanol at room temperature.
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spelling pubmed-90607982022-05-04 Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst Wang, Tao Guo, Jiarui Wang, Xiaojuan Guo, Han Jia, Dingli Wang, Hengjin Liu, Lantao RSC Adv Chemistry N-heterocyclic carbene–palladium(ii)-catalyzed cross-coupling of benzylammonium salts with arylboronic acids for the synthesis of diarylmethane derivatives via C–N bond activation has been developed. Notably, in the presence of the easily prepared and bench-stable Pd-PEPPSI precatalyst, the Csp(3)–N bond activation of the benzylammonium salt even proceeded smoothly in isopropanol at room temperature. The Royal Society of Chemistry 2019-02-15 /pmc/articles/PMC9060798/ /pubmed/35515917 http://dx.doi.org/10.1039/c8ra10439e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Tao
Guo, Jiarui
Wang, Xiaojuan
Guo, Han
Jia, Dingli
Wang, Hengjin
Liu, Lantao
Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title_full Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title_fullStr Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title_full_unstemmed Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title_short Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene–palladium(ii) precatalyst
title_sort cross coupling of benzylammonium salts with boronic acids using a well-defined n-heterocyclic carbene–palladium(ii) precatalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060798/
https://www.ncbi.nlm.nih.gov/pubmed/35515917
http://dx.doi.org/10.1039/c8ra10439e
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