Cargando…
Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins
Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant “chiral pools” of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueo...
Autores principales: | , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060907/ https://www.ncbi.nlm.nih.gov/pubmed/35517290 http://dx.doi.org/10.1039/c8ra10544h |
_version_ | 1784698608996581376 |
---|---|
author | Liang, Dong Wang, Yan Wang, Sifan Song, Chengkun Shi, Yonghe Liu, Qinghao Zhu, Hailin Li, Xia Liu, Laishuan Zhu, Na |
author_facet | Liang, Dong Wang, Yan Wang, Sifan Song, Chengkun Shi, Yonghe Liu, Qinghao Zhu, Hailin Li, Xia Liu, Laishuan Zhu, Na |
author_sort | Liang, Dong |
collection | PubMed |
description | Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant “chiral pools” of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media. |
format | Online Article Text |
id | pubmed-9060907 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90609072022-05-04 Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins Liang, Dong Wang, Yan Wang, Sifan Song, Chengkun Shi, Yonghe Liu, Qinghao Zhu, Hailin Li, Xia Liu, Laishuan Zhu, Na RSC Adv Chemistry Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant “chiral pools” of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media. The Royal Society of Chemistry 2019-02-19 /pmc/articles/PMC9060907/ /pubmed/35517290 http://dx.doi.org/10.1039/c8ra10544h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Liang, Dong Wang, Yan Wang, Sifan Song, Chengkun Shi, Yonghe Liu, Qinghao Zhu, Hailin Li, Xia Liu, Laishuan Zhu, Na Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title | Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title_full | Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title_fullStr | Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title_full_unstemmed | Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title_short | Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
title_sort | well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060907/ https://www.ncbi.nlm.nih.gov/pubmed/35517290 http://dx.doi.org/10.1039/c8ra10544h |
work_keys_str_mv | AT liangdong wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT wangyan wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT wangsifan wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT songchengkun wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT shiyonghe wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT liuqinghao wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT zhuhailin wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT lixia wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT liulaishuan wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins AT zhuna wellconfinedpolyoxometalateionicliquidinsilicicframeworkforenvironmentallyfriendlyasymmetricdihydroxylationofolefins |