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PIDA-mediated intramolecular oxidative C–N bond formation for the direct synthesis of quinoxalines from enaminones

A intramolecular oxidative C(sp(2))–N bond formation mediated by hypervalent iodine(iii) to obtain quinoxalines from readily available N-(2-acetaminophenyl)enaminones was developed. A tandem process involving PIDA-mediated intramolecular condensation cyclization and a subsequent elimination was post...

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Detalles Bibliográficos
Autores principales: Zhang, Hong, Shen, Jinhai, Yang, Zhenhui, Cui, Xiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9061175/
https://www.ncbi.nlm.nih.gov/pubmed/35521175
http://dx.doi.org/10.1039/c9ra01200a