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Mechanism and stereoselectivity in NHC-catalyzed β-functionalization of saturated carboxylic ester
To understand the mechanism and origin of the stereoselectivity of the [3 + 2] annulation reaction between a carboxylic ester and an isatin generating spirooxindole lactone catalyzed by N-heterocyclic carbene (NHC), density functional theory (DFT) calculations have been carried out. DFT results indi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9061211/ https://www.ncbi.nlm.nih.gov/pubmed/35521168 http://dx.doi.org/10.1039/c8ra10262g |