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Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties
In this study, bis(benzoyloxy)dimethylsilane (SDE) was developed as a non-phthalate selectivity control agent (internal donor (ID) and external donor (ED)) in MgCl(2)-supported Ziegler–Natta (ZN) systems. The impact of SDE as an ID was investigated in regards to chemical composition, morphology, ads...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9061220/ https://www.ncbi.nlm.nih.gov/pubmed/35519959 http://dx.doi.org/10.1039/c9ra00715f |
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author | Poorsank, Fatemeh Arabi, Hassan Ghasemi Hamedani, Nona |
author_facet | Poorsank, Fatemeh Arabi, Hassan Ghasemi Hamedani, Nona |
author_sort | Poorsank, Fatemeh |
collection | PubMed |
description | In this study, bis(benzoyloxy)dimethylsilane (SDE) was developed as a non-phthalate selectivity control agent (internal donor (ID) and external donor (ED)) in MgCl(2)-supported Ziegler–Natta (ZN) systems. The impact of SDE as an ID was investigated in regards to chemical composition, morphology, adsorption behavior (using FTIR spectroscopy, WAXD and SEM studies) and the propylene polymerization performance of the catalyst. The results of the adsorption behavior of SDE revealed that SDE, while able to stabilize the electronically unsaturated surfaces of MgCl(2) [(104) and (110)], has a rather high tendency to be absorbed on strongly acidic Mg ions at the corners of these crystals. The catalyst with optimum SDE content as an ID afforded a system with reasonable activity and isotacticity (even in the absence of ED) along with broader molecular weight distribution (PDI: 6.2–10) and greater flexural modulus than phthalate-based ZN systems. SDE was also used as a new ED in most widely used fourth- and fifth-generation catalyst systems. The results revealed that in fifth-generation catalyst systems, there was an increase in hydrogen response (>40%) along with an increase of activity without any change in the thermal properties of the final polymer in comparison to a conventional ED (alkoxy silane). |
format | Online Article Text |
id | pubmed-9061220 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90612202022-05-04 Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties Poorsank, Fatemeh Arabi, Hassan Ghasemi Hamedani, Nona RSC Adv Chemistry In this study, bis(benzoyloxy)dimethylsilane (SDE) was developed as a non-phthalate selectivity control agent (internal donor (ID) and external donor (ED)) in MgCl(2)-supported Ziegler–Natta (ZN) systems. The impact of SDE as an ID was investigated in regards to chemical composition, morphology, adsorption behavior (using FTIR spectroscopy, WAXD and SEM studies) and the propylene polymerization performance of the catalyst. The results of the adsorption behavior of SDE revealed that SDE, while able to stabilize the electronically unsaturated surfaces of MgCl(2) [(104) and (110)], has a rather high tendency to be absorbed on strongly acidic Mg ions at the corners of these crystals. The catalyst with optimum SDE content as an ID afforded a system with reasonable activity and isotacticity (even in the absence of ED) along with broader molecular weight distribution (PDI: 6.2–10) and greater flexural modulus than phthalate-based ZN systems. SDE was also used as a new ED in most widely used fourth- and fifth-generation catalyst systems. The results revealed that in fifth-generation catalyst systems, there was an increase in hydrogen response (>40%) along with an increase of activity without any change in the thermal properties of the final polymer in comparison to a conventional ED (alkoxy silane). The Royal Society of Chemistry 2019-03-06 /pmc/articles/PMC9061220/ /pubmed/35519959 http://dx.doi.org/10.1039/c9ra00715f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Poorsank, Fatemeh Arabi, Hassan Ghasemi Hamedani, Nona Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title | Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title_full | Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title_fullStr | Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title_full_unstemmed | Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title_short | Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties |
title_sort | silyl diol ester as a new selectivity control agent in mgcl(2)-supported ziegler–natta systems for propylene polymerization: catalyst structure and polymer properties |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9061220/ https://www.ncbi.nlm.nih.gov/pubmed/35519959 http://dx.doi.org/10.1039/c9ra00715f |
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