Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex

Solvent-, acidity-, and redox-responsive thione(thiol)–disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC c...

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Detalles Bibliográficos
Autores principales: Jeong, Haewon, Kang, Yeji, Kim, Jin, Kim, Byung-Kwon, Hong, Seungwoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062045/
https://www.ncbi.nlm.nih.gov/pubmed/35517656
http://dx.doi.org/10.1039/c9ra01115c
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author Jeong, Haewon
Kang, Yeji
Kim, Jin
Kim, Byung-Kwon
Hong, Seungwoo
author_facet Jeong, Haewon
Kang, Yeji
Kim, Jin
Kim, Byung-Kwon
Hong, Seungwoo
author_sort Jeong, Haewon
collection PubMed
description Solvent-, acidity-, and redox-responsive thione(thiol)–disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.
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spelling pubmed-90620452022-05-04 Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex Jeong, Haewon Kang, Yeji Kim, Jin Kim, Byung-Kwon Hong, Seungwoo RSC Adv Chemistry Solvent-, acidity-, and redox-responsive thione(thiol)–disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions. The Royal Society of Chemistry 2019-03-19 /pmc/articles/PMC9062045/ /pubmed/35517656 http://dx.doi.org/10.1039/c9ra01115c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Jeong, Haewon
Kang, Yeji
Kim, Jin
Kim, Byung-Kwon
Hong, Seungwoo
Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title_full Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title_fullStr Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title_full_unstemmed Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title_short Factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
title_sort factors that determine thione(thiol)–disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062045/
https://www.ncbi.nlm.nih.gov/pubmed/35517656
http://dx.doi.org/10.1039/c9ra01115c
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