The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system

Transport of Ag(i), Cd(ii), Co(ii), Cu(ii), Ni(ii), Pb(ii) and Zn(ii) cations across a bulk liquid membrane (BLM) containing N,N′-dibenzyl-N′′-(2,2,2-trifluoroacetyl)-phosphoric triamide (PTC) as a new carrier is studied by atomic absorption spectrometry. The results show selective and efficient tra...

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Autores principales: Akbari, Setareh, Khoshnood, Razieh Sanavi, Ahmadabad, Fatemeh Karimi, Pourayoubi, Mehrdad, Dušek, Michal, Shchegravina, Ekaterina S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062073/
https://www.ncbi.nlm.nih.gov/pubmed/35517695
http://dx.doi.org/10.1039/c8ra09118h
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author Akbari, Setareh
Khoshnood, Razieh Sanavi
Ahmadabad, Fatemeh Karimi
Pourayoubi, Mehrdad
Dušek, Michal
Shchegravina, Ekaterina S.
author_facet Akbari, Setareh
Khoshnood, Razieh Sanavi
Ahmadabad, Fatemeh Karimi
Pourayoubi, Mehrdad
Dušek, Michal
Shchegravina, Ekaterina S.
author_sort Akbari, Setareh
collection PubMed
description Transport of Ag(i), Cd(ii), Co(ii), Cu(ii), Ni(ii), Pb(ii) and Zn(ii) cations across a bulk liquid membrane (BLM) containing N,N′-dibenzyl-N′′-(2,2,2-trifluoroacetyl)-phosphoric triamide (PTC) as a new carrier is studied by atomic absorption spectrometry. The results show selective and efficient transport of the copper(ii) cation from aqueous solution in the presence of the other cations. Various factors are optimized in order to obtain maximum transport efficiency. The PTC ligand is characterized by single crystal X-ray diffraction analysis, IR, NMR ((19)F, (31)P, (1)H, (13)C) and mass spectroscopy. The complex formation reaction between copper(ii) and PTC is studied by a conductometric method, which shows the 1 : 1 stoichiometry for ligand and copper(ii).
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spelling pubmed-90620732022-05-04 The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system Akbari, Setareh Khoshnood, Razieh Sanavi Ahmadabad, Fatemeh Karimi Pourayoubi, Mehrdad Dušek, Michal Shchegravina, Ekaterina S. RSC Adv Chemistry Transport of Ag(i), Cd(ii), Co(ii), Cu(ii), Ni(ii), Pb(ii) and Zn(ii) cations across a bulk liquid membrane (BLM) containing N,N′-dibenzyl-N′′-(2,2,2-trifluoroacetyl)-phosphoric triamide (PTC) as a new carrier is studied by atomic absorption spectrometry. The results show selective and efficient transport of the copper(ii) cation from aqueous solution in the presence of the other cations. Various factors are optimized in order to obtain maximum transport efficiency. The PTC ligand is characterized by single crystal X-ray diffraction analysis, IR, NMR ((19)F, (31)P, (1)H, (13)C) and mass spectroscopy. The complex formation reaction between copper(ii) and PTC is studied by a conductometric method, which shows the 1 : 1 stoichiometry for ligand and copper(ii). The Royal Society of Chemistry 2019-03-19 /pmc/articles/PMC9062073/ /pubmed/35517695 http://dx.doi.org/10.1039/c8ra09118h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Akbari, Setareh
Khoshnood, Razieh Sanavi
Ahmadabad, Fatemeh Karimi
Pourayoubi, Mehrdad
Dušek, Michal
Shchegravina, Ekaterina S.
The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title_full The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title_fullStr The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title_full_unstemmed The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title_short The (CF(3)C(O)NH)(C(6)H(5)CH(2)NH)(2)P(O) phosphoric triamide as a novel carrier with excellent efficiency for Cu(ii) in a liquid membrane transport system
title_sort (cf(3)c(o)nh)(c(6)h(5)ch(2)nh)(2)p(o) phosphoric triamide as a novel carrier with excellent efficiency for cu(ii) in a liquid membrane transport system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062073/
https://www.ncbi.nlm.nih.gov/pubmed/35517695
http://dx.doi.org/10.1039/c8ra09118h
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