The Dopamine Assisted Synthesis of MoO(3)/Carbon Electrodes With Enhanced Capacitance in Aqueous Electrolyte

A capacitance increase phenomenon is observed for MoO(3) electrodes synthesized via a sol-gel process in the presence of dopamine hydrochloride (Dopa HCl) as compared to α-MoO(3) electrodes in 5M ZnCl(2) aqueous electrolyte. The synthesis approach is based on a hydrogen peroxide-initiated sol-gel reaction to which the Dopa HCl is added. The powder precursor (Dopa)(x)MoO(y), is isolated from the metastable gel using freeze-drying. Hydrothermal treatment (HT) of the precursor results in the formation of MoO(3) accompanied by carbonization of the organic molecules; designated as HT-MoO(3)/C. HT of the precipitate formed in the absence of dopamine in the reaction produced α-MoO(3), which was used as a reference material in this study (α-MoO(3)-ref). Scanning electron microscopy (SEM) images show a nanobelt morphology for both HT-MoO(3)/C and α-MoO(3)-ref powders, but with distinct differences in the shape of the nanobelts. The presence of carbonaceous content in the structure of HT-MoO(3)/C is confirmed by FTIR and Raman spectroscopy measurements. X-ray diffraction (XRD) and Rietveld refinement analysis demonstrate the presence of α-MoO(3) and h-MoO(3) phases in the structure of HT-MoO(3)/C. The increased specific capacitance delivered by the HT-MoO(3)/C electrode as compared to the α-MoO(3)-ref electrode in 5M ZnCl(2) electrolyte in a −0.25–0.70 V vs. Ag/AgCl potential window triggered a more detailed study in an expanded potential window. In the 5M ZnCl(2) electrolyte at a scan rate of 2 mV s(−1), the HT-MoO(3)/C electrode shows a second cycle capacitance of 347.6 F g(−1). The higher electrochemical performance of the HT-MoO(3)/C electrode can be attributed to the presence of carbon in its structure, which can facilitate electron transport. Our study provides a new route for further development of metal oxides for energy storage applications.