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Synthesis of d-glyco-alkynone derivatives via carbonylative Sonogashira reaction

A carbonylative Sonogashira coupling approach to the synthesis of glyco-alkynones is described. Eighteen examples were obtained in moderate do nearly quantitative yields under mild conditions employing Mo(CO)(6) as a safe carbon monoxide source. Functionalization of the alkynyl moiety via cycloaddit...

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Detalles Bibliográficos
Autores principales: Darbem, Mariana P., Esteves, C. Henrique A., de Oliveira, Isadora M., Reis, Joel S., Pimenta, Daniel C., Stefani, Hélio A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062118/
https://www.ncbi.nlm.nih.gov/pubmed/35520747
http://dx.doi.org/10.1039/c9ra00523d

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