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Electron beam-based fabrication of crosslinked hydrophilic carbon electrodes and their application for capacitive deionization
In this research, we demonstrated that a crosslinked hydrophilic carbon electrode with better electrochemical performance than hydrophobic counterparts can easily be produced using room-temperature, quick electron-beam irradiation with a hydrophilic methacryloyl-substituted polyvinyl alcohol (SPVA)...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062162/ https://www.ncbi.nlm.nih.gov/pubmed/35520723 http://dx.doi.org/10.1039/c8ra10527h |
Sumario: | In this research, we demonstrated that a crosslinked hydrophilic carbon electrode with better electrochemical performance than hydrophobic counterparts can easily be produced using room-temperature, quick electron-beam irradiation with a hydrophilic methacryloyl-substituted polyvinyl alcohol (SPVA) binder. The SPVA binder was effectively synthesized by trans-esterification of PVA with glycidyl methacrylate. The hydrophilic carbon electrode cast on a graphite sheet from a slurry of activated carbon (AC) and SPVA was irradiated with an electron beam to form a crosslinked structure. The analytical results in terms of the morphology, solvent resistance, chemical composition, and contact angle revealed that the carbon electrode was completely crosslinked by electron-beam irradiation even at the dose of 100 kGy (irradiation time = 180 s). The new electrode exhibited superior water-wettability due to the hydrophilic functionality of SPVA. Furthermore, the hydrophilic carbon electrode with an AC : SPVA composition of 90 : 10 and an absorbed dose of 200 kGy, exhibited a specific capacitance of 127 F g(−1) (67% higher than the hydrophobic poly(vinylidene fluoride) (PVDF)-based counterpart with the same composition). The specific capacitance was further improved to 160 F g(−1) with an increase in the AC content. The hydrophilic carbon electrode exhibited noticeably better desalination efficiency than the hydrophobic PVDF-based counterpart. |
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