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Redox activity of nickel and vanadium porphyrins: a possible mechanism behind petroleum genesis and maturation?
The presence of metalloporphyrins in crude oil has been known for many years. In contrast, their role on the physical–chemical properties is only now beginning to be understood. In this study, we test using high-level ab initio calculations, the hypothesis of a possible redox catalytic activity of v...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062163/ https://www.ncbi.nlm.nih.gov/pubmed/35520708 http://dx.doi.org/10.1039/c9ra01104h |