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Alkyl coupling in tertiary amines as analog of Guerbet condensation reaction
We report here that C–C coupling in tertiary amines for the synthesis of long chain and hindered amines might be efficiently performed over Pt and Pd catalysts. The mechanism study confirms similarity with the Guerbet reaction through dehydrogenation of the alkyl group and subsequent attack of the α...
Autores principales: | Zhou, Yage, Wu, Dan, Hernández, Willinton Yesid, Ma, Changru, Su, Huangyang, Ordomsky, Vitaly |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9062200/ https://www.ncbi.nlm.nih.gov/pubmed/35520721 http://dx.doi.org/10.1039/c8ra08316a |
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