Biosorption of anionic and cationic dyes via raw and chitosan oligosaccharide-modified Huai Flos Chrysanthemum at different temperatures

Raw Huai Flos Chrysanthemum (HFC) and modified HFC (HFC@CO) were used for the first time as a biosorbent material to remove cationic dyes Malachite green (MG) and Crystal violet (CV), and anionic dyes Sunset yellow (SY), Lemon yellow (LY), and Carmine (CM), at different temperatures (5–50 °C). The highest removal rates (R) for dye adsorption were observed at low temperature (5 °C) and room temperature (20 °C). At high (500 mg L(−1)) dye concentration, adsorption was completed within one minute, but the time required to reach adsorption equilibrium was longer than at the low (20 mg L(−1)) concentration. The experimental data fitted very well to the Langmuir model and the values of the maximum adsorption capacity for SY, LY, CM, CV, and MG, were 481.41, 507.23, 141.78 mg g(−1), 526.32, and 769.23 mg L(−1), respectively. The adsorption data fit well to a pseudo-second-order kinetic model.