Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC

Chirality at a supramolecular level is currently attracting great attention attributed to rapid developments in supramolecular chemistry. Herein, we report a new type of chiral self-assembly based on the cyanine dye MTC. The chiral H-aggregates of MTC could form spontaneously from achiral J-aggregat...

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Detalles Bibliográficos
Autores principales: Guan, Ai-Jiao, Zhang, Jing-Tao, Wang, Li-Xia, Cui, Jie, Xiang, Jun-Feng, Sun, Xin, Chen, Kuo, Li, Qian, Tang, Ya-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063261/
https://www.ncbi.nlm.nih.gov/pubmed/35520237
http://dx.doi.org/10.1039/c9ra00063a
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author Guan, Ai-Jiao
Zhang, Jing-Tao
Wang, Li-Xia
Cui, Jie
Xiang, Jun-Feng
Sun, Xin
Chen, Kuo
Li, Qian
Tang, Ya-Lin
author_facet Guan, Ai-Jiao
Zhang, Jing-Tao
Wang, Li-Xia
Cui, Jie
Xiang, Jun-Feng
Sun, Xin
Chen, Kuo
Li, Qian
Tang, Ya-Lin
author_sort Guan, Ai-Jiao
collection PubMed
description Chirality at a supramolecular level is currently attracting great attention attributed to rapid developments in supramolecular chemistry. Herein, we report a new type of chiral self-assembly based on the cyanine dye MTC. The chiral H-aggregates of MTC could form spontaneously from achiral J-aggregates, and could return back to achiral J-aggregates in high concentration on increasing the solution temperature.
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spelling pubmed-90632612022-05-04 Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC Guan, Ai-Jiao Zhang, Jing-Tao Wang, Li-Xia Cui, Jie Xiang, Jun-Feng Sun, Xin Chen, Kuo Li, Qian Tang, Ya-Lin RSC Adv Chemistry Chirality at a supramolecular level is currently attracting great attention attributed to rapid developments in supramolecular chemistry. Herein, we report a new type of chiral self-assembly based on the cyanine dye MTC. The chiral H-aggregates of MTC could form spontaneously from achiral J-aggregates, and could return back to achiral J-aggregates in high concentration on increasing the solution temperature. The Royal Society of Chemistry 2019-04-11 /pmc/articles/PMC9063261/ /pubmed/35520237 http://dx.doi.org/10.1039/c9ra00063a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Guan, Ai-Jiao
Zhang, Jing-Tao
Wang, Li-Xia
Cui, Jie
Xiang, Jun-Feng
Sun, Xin
Chen, Kuo
Li, Qian
Tang, Ya-Lin
Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title_full Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title_fullStr Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title_full_unstemmed Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title_short Spontaneous formation and reversible transformation between achiral J- and chiral H-aggregates of cyanine dye MTC
title_sort spontaneous formation and reversible transformation between achiral j- and chiral h-aggregates of cyanine dye mtc
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063261/
https://www.ncbi.nlm.nih.gov/pubmed/35520237
http://dx.doi.org/10.1039/c9ra00063a
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