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Novel asymmetric photodimerization reaction of coumarin derivatives bearing a chiral 2-oxazolidinone auxiliary

A novel asymmetric photodimerization reaction of coumarin derivatives bearing the (S)-4-benzyl-2-oxazolidinone auxiliary provides only the syn-head-to-tail (syn-HT) dimer with moderate diastereoselectivity (up to 75 : 25). The mechanism of complete syn-HT selectivity and moderate diastereoselectivit...

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Detalles Bibliográficos
Autores principales: Itoh, Kennosuke, Odate, Fumiya, Karikomi, Takuma, Obe, Keishi, Miyamori, Tsutomu, Kamiya, Hideaki, Yoza, Kenji, Nagai, Kenichiro, Fujii, Hideaki, Suga, Hiroyuki, Tokunaga, Ken
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063662/
https://www.ncbi.nlm.nih.gov/pubmed/35515875
http://dx.doi.org/10.1039/c9ra00822e

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