Identification of different carbenium ion intermediates in zeolites with identical chabazite topology via(13)C–(13)C through-bond NMR correlations

(13)C–(13)C through-bond NMR correlation experiments reveal the stabilization of different carbenium ion intermediates in two zeolites possessing identical CHA topology (H-SAPO-34 and H-SSZ-13) during the methanol to olefins reaction.

Detalles Bibliográficos
Autores principales: Xiao, Dong, Han, Xiuwen, Bao, Xinhe, Hou, Guangjin, Blanc, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063671/
https://www.ncbi.nlm.nih.gov/pubmed/35515828
http://dx.doi.org/10.1039/c9ra02280e
Descripción
Sumario:(13)C–(13)C through-bond NMR correlation experiments reveal the stabilization of different carbenium ion intermediates in two zeolites possessing identical CHA topology (H-SAPO-34 and H-SSZ-13) during the methanol to olefins reaction.

Ejemplares similares