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Incorporating polyoxometalates and organic ligands to pursue 3d–4f heterometallic clusters: a series of {Cr(4)Ln(4)} clusters stabilized by phthalic acid and [SiW(12)O(40)](4−)

By introduction of trilacunary Keggin-type polyoxometalate to the hydrothermal reaction system of Cr(3+), Ln(3+) and phthalic acid, a series of novel {Cr(4)Ln(4)} heterometallic clusters with the formula Cs(2)[Cr(4)Ln(4)(μ(4)-O)(4)(μ(3)-O)(4)(C(8)H(4)O(4))(4)(H(2)O)(12)](H(3)SiW(12)O(40))Cl·23H(2)O...

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Detalles Bibliográficos
Autores principales: Gu, Ya-Nan, Zhao, Dan, Yu, Hao, Ge, Rui, Li, Zhong, Tian, Chong-Bian, Li, Xin-Xiong, Sun, Yan-Qiong, Zheng, Shou-Tian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063906/
https://www.ncbi.nlm.nih.gov/pubmed/35519577
http://dx.doi.org/10.1039/c9ra01731c