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Incorporating polyoxometalates and organic ligands to pursue 3d–4f heterometallic clusters: a series of {Cr(4)Ln(4)} clusters stabilized by phthalic acid and [SiW(12)O(40)](4−)
By introduction of trilacunary Keggin-type polyoxometalate to the hydrothermal reaction system of Cr(3+), Ln(3+) and phthalic acid, a series of novel {Cr(4)Ln(4)} heterometallic clusters with the formula Cs(2)[Cr(4)Ln(4)(μ(4)-O)(4)(μ(3)-O)(4)(C(8)H(4)O(4))(4)(H(2)O)(12)](H(3)SiW(12)O(40))Cl·23H(2)O...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063906/ https://www.ncbi.nlm.nih.gov/pubmed/35519577 http://dx.doi.org/10.1039/c9ra01731c |