Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis

Cooperative catalysis on solid surfaces relies primarily on two or more catalytic partners being close enough to each other to sustain the catalytic cycle. We describe here the synthesis and preliminary investigation of discrete homo-oligomers as flexible scaffolds to inflect the intersite distance...

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Detalles Bibliográficos
Autores principales: Chandra, Prakash, Jonas, Alain M., Fernandes, Antony E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064013/
https://www.ncbi.nlm.nih.gov/pubmed/35519338
http://dx.doi.org/10.1039/c9ra00847k
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author Chandra, Prakash
Jonas, Alain M.
Fernandes, Antony E.
author_facet Chandra, Prakash
Jonas, Alain M.
Fernandes, Antony E.
author_sort Chandra, Prakash
collection PubMed
description Cooperative catalysis on solid surfaces relies primarily on two or more catalytic partners being close enough to each other to sustain the catalytic cycle. We describe here the synthesis and preliminary investigation of discrete homo-oligomers as flexible scaffolds to inflect the intersite distance and blur the compositional heterogeneity in a silica-grafted catalytic triad.
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spelling pubmed-90640132022-05-04 Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis Chandra, Prakash Jonas, Alain M. Fernandes, Antony E. RSC Adv Chemistry Cooperative catalysis on solid surfaces relies primarily on two or more catalytic partners being close enough to each other to sustain the catalytic cycle. We describe here the synthesis and preliminary investigation of discrete homo-oligomers as flexible scaffolds to inflect the intersite distance and blur the compositional heterogeneity in a silica-grafted catalytic triad. The Royal Society of Chemistry 2019-05-07 /pmc/articles/PMC9064013/ /pubmed/35519338 http://dx.doi.org/10.1039/c9ra00847k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Chandra, Prakash
Jonas, Alain M.
Fernandes, Antony E.
Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title_full Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title_fullStr Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title_full_unstemmed Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title_short Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
title_sort synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064013/
https://www.ncbi.nlm.nih.gov/pubmed/35519338
http://dx.doi.org/10.1039/c9ra00847k
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AT fernandesantonye synthesisofdiscretecatalyticoligomersandtheirpotentialinsilicasupportedcooperativecatalysis

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