Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials

A repeatable self-healing epoxy composite mechanically enhanced by graphene nanosheets (GNS) was prepared from an epoxy monomer with Diels–Alder (DA) bonds, octanediol glycidyl ether (OGE) and polyether amine (D230). The GNS/epoxy composites, with a maximum tensile modulus of 14.52 ± 0.45 MPa and el...

Descripción completa

Detalles Bibliográficos
Autores principales: Guo, Yakun, Zou, Dongli, Zhu, Wanqiu, Yang, Xiaojiao, Zhao, Pengxiang, Chen, Changan, Shuai, Maobing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064049/
https://www.ncbi.nlm.nih.gov/pubmed/35519330
http://dx.doi.org/10.1039/c9ra00261h
_version_ 1784699283441713152
author Guo, Yakun
Zou, Dongli
Zhu, Wanqiu
Yang, Xiaojiao
Zhao, Pengxiang
Chen, Changan
Shuai, Maobing
author_facet Guo, Yakun
Zou, Dongli
Zhu, Wanqiu
Yang, Xiaojiao
Zhao, Pengxiang
Chen, Changan
Shuai, Maobing
author_sort Guo, Yakun
collection PubMed
description A repeatable self-healing epoxy composite mechanically enhanced by graphene nanosheets (GNS) was prepared from an epoxy monomer with Diels–Alder (DA) bonds, octanediol glycidyl ether (OGE) and polyether amine (D230). The GNS/epoxy composites, with a maximum tensile modulus of 14.52 ± 0.45 MPa and elongation at break more than 100%, could be healed several times under Infrared (IR) light with the healing efficiency as high as 90% through the molecule chain mobility and the rebonding of reversible DA bonds between furan and maleimide. Also, they displayed excellent recyclable ability by transforming into a soluble polymer, which offers a wide range of possibilities to produce epoxy flexible materials with healing and removable abilities.
format Online
Article
Text
id pubmed-9064049
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90640492022-05-04 Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials Guo, Yakun Zou, Dongli Zhu, Wanqiu Yang, Xiaojiao Zhao, Pengxiang Chen, Changan Shuai, Maobing RSC Adv Chemistry A repeatable self-healing epoxy composite mechanically enhanced by graphene nanosheets (GNS) was prepared from an epoxy monomer with Diels–Alder (DA) bonds, octanediol glycidyl ether (OGE) and polyether amine (D230). The GNS/epoxy composites, with a maximum tensile modulus of 14.52 ± 0.45 MPa and elongation at break more than 100%, could be healed several times under Infrared (IR) light with the healing efficiency as high as 90% through the molecule chain mobility and the rebonding of reversible DA bonds between furan and maleimide. Also, they displayed excellent recyclable ability by transforming into a soluble polymer, which offers a wide range of possibilities to produce epoxy flexible materials with healing and removable abilities. The Royal Society of Chemistry 2019-05-07 /pmc/articles/PMC9064049/ /pubmed/35519330 http://dx.doi.org/10.1039/c9ra00261h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Guo, Yakun
Zou, Dongli
Zhu, Wanqiu
Yang, Xiaojiao
Zhao, Pengxiang
Chen, Changan
Shuai, Maobing
Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title_full Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title_fullStr Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title_full_unstemmed Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title_short Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
title_sort infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064049/
https://www.ncbi.nlm.nih.gov/pubmed/35519330
http://dx.doi.org/10.1039/c9ra00261h
work_keys_str_mv AT guoyakun infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT zoudongli infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT zhuwanqiu infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT yangxiaojiao infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT zhaopengxiang infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT chenchangan infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials
AT shuaimaobing infraredinducedrepeatableselfhealingandremovabilityofmechanicallyenhancedgrapheneepoxyflexiblematerials

Ejemplares similares