Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure

Vanadium phosphate oxide (VPO) heterogeneous catalysts with different V/P molar ratios were prepared and used for selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-diformylfuran (DFF) in the liquid phase. It was found that the VPO catalyst with V/P molar ratio 0.25...

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Detalles Bibliográficos
Autores principales: Lai, Jinhua, Liu, Kai, Zhou, Shuolin, Zhang, Du, Liu, Xianxiang, Xu, Qiong, Yin, Dulin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064058/
https://www.ncbi.nlm.nih.gov/pubmed/35519318
http://dx.doi.org/10.1039/c9ra02213a
Descripción
Sumario:Vanadium phosphate oxide (VPO) heterogeneous catalysts with different V/P molar ratios were prepared and used for selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-diformylfuran (DFF) in the liquid phase. It was found that the VPO catalyst with V/P molar ratio 0.25 exhibited the best catalytic performance. Then the VPO catalyst was utilized to catalyze the oxidation of HMF in a batch reactor under different conditions, in terms of type of solvent (water and organic), reaction time and temperature. A high DFF yield of 83.6% with HMF conversion of 100% was obtained under atmospheric pressure.

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