Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure

Vanadium phosphate oxide (VPO) heterogeneous catalysts with different V/P molar ratios were prepared and used for selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-diformylfuran (DFF) in the liquid phase. It was found that the VPO catalyst with V/P molar ratio 0.25...

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Autores principales: Lai, Jinhua, Liu, Kai, Zhou, Shuolin, Zhang, Du, Liu, Xianxiang, Xu, Qiong, Yin, Dulin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064058/
https://www.ncbi.nlm.nih.gov/pubmed/35519318
http://dx.doi.org/10.1039/c9ra02213a
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author Lai, Jinhua
Liu, Kai
Zhou, Shuolin
Zhang, Du
Liu, Xianxiang
Xu, Qiong
Yin, Dulin
author_facet Lai, Jinhua
Liu, Kai
Zhou, Shuolin
Zhang, Du
Liu, Xianxiang
Xu, Qiong
Yin, Dulin
author_sort Lai, Jinhua
collection PubMed
description Vanadium phosphate oxide (VPO) heterogeneous catalysts with different V/P molar ratios were prepared and used for selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-diformylfuran (DFF) in the liquid phase. It was found that the VPO catalyst with V/P molar ratio 0.25 exhibited the best catalytic performance. Then the VPO catalyst was utilized to catalyze the oxidation of HMF in a batch reactor under different conditions, in terms of type of solvent (water and organic), reaction time and temperature. A high DFF yield of 83.6% with HMF conversion of 100% was obtained under atmospheric pressure.
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spelling pubmed-90640582022-05-04 Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure Lai, Jinhua Liu, Kai Zhou, Shuolin Zhang, Du Liu, Xianxiang Xu, Qiong Yin, Dulin RSC Adv Chemistry Vanadium phosphate oxide (VPO) heterogeneous catalysts with different V/P molar ratios were prepared and used for selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-diformylfuran (DFF) in the liquid phase. It was found that the VPO catalyst with V/P molar ratio 0.25 exhibited the best catalytic performance. Then the VPO catalyst was utilized to catalyze the oxidation of HMF in a batch reactor under different conditions, in terms of type of solvent (water and organic), reaction time and temperature. A high DFF yield of 83.6% with HMF conversion of 100% was obtained under atmospheric pressure. The Royal Society of Chemistry 2019-05-07 /pmc/articles/PMC9064058/ /pubmed/35519318 http://dx.doi.org/10.1039/c9ra02213a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Lai, Jinhua
Liu, Kai
Zhou, Shuolin
Zhang, Du
Liu, Xianxiang
Xu, Qiong
Yin, Dulin
Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title_full Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title_fullStr Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title_full_unstemmed Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title_short Selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over VPO catalysts under atmospheric pressure
title_sort selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran over vpo catalysts under atmospheric pressure
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064058/
https://www.ncbi.nlm.nih.gov/pubmed/35519318
http://dx.doi.org/10.1039/c9ra02213a
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