Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(i) complex in aqueous media

New simple, fast, effective and environmentally friendly one-pot method for the synthesis of extensively used tetrakis(acetonitrile)copper(i) complexes with BF(4)(−), PF(6)(−) and ClO(4)(−) counterions is invented and optimized. The approach suggested allows using water as solvent and minimizes amou...

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Detalles Bibliográficos
Autores principales: Kritchenkov, Ilya S., Shakirova, Julia R., Tunik, Sergey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064342/
https://www.ncbi.nlm.nih.gov/pubmed/35514835
http://dx.doi.org/10.1039/c8ra10564b
Descripción
Sumario:New simple, fast, effective and environmentally friendly one-pot method for the synthesis of extensively used tetrakis(acetonitrile)copper(i) complexes with BF(4)(−), PF(6)(−) and ClO(4)(−) counterions is invented and optimized. The approach suggested allows using water as solvent and minimizes amounts of toxic organic reagents in the synthetic protocol.

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