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Solvent-driven structural topology involving energetically significant intra- and intermolecular chelate ring contacts and anticancer activities of Cu(ii) phenanthroline complexes involving benzoates: experimental and theoretical studies
Two new coordination solids [Cu(2)(μ(2)-Bz)(4)(CH(3)OH)(2)][Cu(2)(η(2)-Bz)(2)(phen)(2)(H(2)O)(2)]·(NO(3))(2) (1) and [Cu(phen)(H(2)O)(Bz)(η(2)-Bz)] (2) (phen = 1,10-phenanthroline; Bz = benzoate) have been synthesized and characterized using elemental analysis, TGA, spectroscopic (IR, UV-vis-NIR and...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064362/ https://www.ncbi.nlm.nih.gov/pubmed/35516385 http://dx.doi.org/10.1039/c9ra01181a |