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Mechanism of atom economical conversion of alcohols and amines to amides using Fe(ii) pincer catalyst. An outer-sphere metal–ligand pathway or an inner-sphere elimination pathway?
In this present theoretical study, we investigated the reaction mechanism of atom-economical amide formation from alcohols and amines mediated by iron(ii) hydride complex ((iPr)PNP)Fe(H)(CO) ((iPr)PNP = N[CH(2)CH(2)(PiPr(2))](2)) using state-of-the-art density functional theory. Two scenarios of mec...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064549/ https://www.ncbi.nlm.nih.gov/pubmed/35519856 http://dx.doi.org/10.1039/c9ra03309b |