Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes

N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solve...

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Autores principales: Nagata, Tatsuki, Inoue, Takeru, Lin, Xianjin, Ishimoto, Shinya, Nakamichi, Seiya, Oka, Hideo, Kondo, Ryota, Suzuki, Takeyuki, Obora, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064576/
https://www.ncbi.nlm.nih.gov/pubmed/35519839
http://dx.doi.org/10.1039/c9ra02895a
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author Nagata, Tatsuki
Inoue, Takeru
Lin, Xianjin
Ishimoto, Shinya
Nakamichi, Seiya
Oka, Hideo
Kondo, Ryota
Suzuki, Takeyuki
Obora, Yasushi
author_facet Nagata, Tatsuki
Inoue, Takeru
Lin, Xianjin
Ishimoto, Shinya
Nakamichi, Seiya
Oka, Hideo
Kondo, Ryota
Suzuki, Takeyuki
Obora, Yasushi
author_sort Nagata, Tatsuki
collection PubMed
description N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.
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spelling pubmed-90645762022-05-04 Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes Nagata, Tatsuki Inoue, Takeru Lin, Xianjin Ishimoto, Shinya Nakamichi, Seiya Oka, Hideo Kondo, Ryota Suzuki, Takeyuki Obora, Yasushi RSC Adv Chemistry N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions. The Royal Society of Chemistry 2019-06-03 /pmc/articles/PMC9064576/ /pubmed/35519839 http://dx.doi.org/10.1039/c9ra02895a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Nagata, Tatsuki
Inoue, Takeru
Lin, Xianjin
Ishimoto, Shinya
Nakamichi, Seiya
Oka, Hideo
Kondo, Ryota
Suzuki, Takeyuki
Obora, Yasushi
Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title_full Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title_fullStr Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title_full_unstemmed Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title_short Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
title_sort dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064576/
https://www.ncbi.nlm.nih.gov/pubmed/35519839
http://dx.doi.org/10.1039/c9ra02895a
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