Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation

Site-selective synthesis of C-7 arylated indolines has been achieved via oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C–H activation of indolines by using CuSO(4) as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions....

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Detalles Bibliográficos
Autores principales: Luo, Haiqing, Xie, Qi, Sun, Kai, Deng, Jianbo, Xu, Lin, Wang, Kejun, Luo, Xuzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064675/
https://www.ncbi.nlm.nih.gov/pubmed/35515217
http://dx.doi.org/10.1039/c9ra04142g
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author Luo, Haiqing
Xie, Qi
Sun, Kai
Deng, Jianbo
Xu, Lin
Wang, Kejun
Luo, Xuzhong
author_facet Luo, Haiqing
Xie, Qi
Sun, Kai
Deng, Jianbo
Xu, Lin
Wang, Kejun
Luo, Xuzhong
author_sort Luo, Haiqing
collection PubMed
description Site-selective synthesis of C-7 arylated indolines has been achieved via oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C–H activation of indolines by using CuSO(4) as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions.
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spelling pubmed-90646752022-05-04 Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation Luo, Haiqing Xie, Qi Sun, Kai Deng, Jianbo Xu, Lin Wang, Kejun Luo, Xuzhong RSC Adv Chemistry Site-selective synthesis of C-7 arylated indolines has been achieved via oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C–H activation of indolines by using CuSO(4) as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions. The Royal Society of Chemistry 2019-06-10 /pmc/articles/PMC9064675/ /pubmed/35515217 http://dx.doi.org/10.1039/c9ra04142g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Luo, Haiqing
Xie, Qi
Sun, Kai
Deng, Jianbo
Xu, Lin
Wang, Kejun
Luo, Xuzhong
Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title_full Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title_fullStr Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title_full_unstemmed Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title_short Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
title_sort rh(iii)-catalyzed c-7 arylation of indolines with arylsilanes via c–h activation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064675/
https://www.ncbi.nlm.nih.gov/pubmed/35515217
http://dx.doi.org/10.1039/c9ra04142g
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