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Systematic study of the substitution effect on the tetrel bond between 1,4-diazabicyclo[2.2.2]octane and TH(3)X
A tetrel bond was characterized in the complexes of 1,4-diazabicyclo[2.2.2]octane (DABCO) with TH(3)X (T = C, Si, Ge; X= –Me, –H, –OH, –NH(2), –F, –Cl, –Br, –I, –CN, –NO(2)). DABCO engages in a weak tetrel bond with CH(3)X but a stronger one with SiH(3)X and GeH(3)X. SiH(3)X is favorable to bind wit...
Autores principales: | Hou, Mingchang, Jin, Kunyu, Li, Qingzhong, Liu, Shufeng |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064731/ https://www.ncbi.nlm.nih.gov/pubmed/35515262 http://dx.doi.org/10.1039/c9ra03351c |
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